9080's at 6V on a 700? Holy smokes that's low on torque!
I tried an old set of those in my E5 and they lacked the torque needed to center properly in loaded flight maneuvers and just left the heli feeling very sluggish. Try the Align HV's you have and don't forget to drop the gain down again.
Also note that vbar Agility isn't a fixed roll rate setting (100 on one setup will not roll the same rate as another setup or heli). It's close, but only based on 8 degrees and assuming specific geometry. For the kind of cyclic you appear to desire, check your swash ring (setup>swash>advanced) to verify
max cyclic and that you're seeing around 14 degrees aileron, at center collective. Then start at Agility of 90 and increase as needed. Each time you change the Agility you need to re-run the optimizers for a couple of max rate rolls/flips with hard stops in between. That will fine tune the start gains necessary to achieve the desired Agility off center. (Rumor has it this will also adjust stopping behavior as well).
If you find the roll rate is great but want just a little more quickness off center, bump up the paddle sim even further (40). Similar to pitch pump, it's a parameter that needs increments of 10 to notice the change.
I second Ben's advice on adding a little pitch pump (start with 20) to increase your collective stops in rainbows, etc. It's a dynamic reverse expo and likes quick fingers.
